Volume 10, Issue 1, February 2020

Regular issue 10 (1) 2020


Relationship of the t/(K1C/σ0.2)2 and hmax/t criteria for materials in the bcc lattice (dark dots), fcc lattice (light dots) and hcp lattice (combined dots) in CG state (1-4, 7-9, 11, 14) and also in the UFG state (5, 6, 10, 12, 13, 15). The vertical line meets the criterion t/(K1C/σ0.2)2 ≥ 2.5.
1 – С20; 2 – С40; 3 – Fe-0.15C-2Cr-1Mo-1V; 4 – 9MnSi5; 5 – С45 (ECAP); 6 - 9MnSi5 (ECAP); 7 – ENAW-2024; 8 – Fe-0.03C-13Cr-0.1N-19Mn; 9 – ENAW-2618A; 10 – ENAW-2618A (ECAP); 11 – Ti-6Al-4V; 12 – Ti-6Al-4V (ECAP); 13 – Ti-6Al-4V (ECAP + IS); 14 – Ti-6Al-4Mo; 15 – Ti-6Al-4Mo (HR)

Local stress state of materials with an hcp lattice and plastic zones under the fracture surface

Relationship of the t/(K1C/σ0.2)2 and hmax/t criteria for materials in the bcc lattice (dark dots), fcc lattice (light dots) and hcp lattice (combined dots) in CG state (1-4, 7-9, 11, 14) and also in the UFG state (5, 6, 10, 12, 13, 15). The vertical line meets the criterion t/(K1C/σ0.2)2 ≥ 2.5. 1 – С20; 2 – С40; 3 – Fe-0.15C-2Cr-1Mo-1V; 4 – 9MnSi5; 5 – С45 (ECAP); 6 - 9MnSi5 (ECAP); 7 – ENAW-2024; 8 – Fe-0.03C-13Cr-0.1N-19Mn; 9 – ENAW-2618A; 10 – ENAW-2618A (ECAP); 11 – Ti-6Al-4V; 12 – Ti-6Al-4V (ECAP); 13 – Ti-6Al-4V (ECAP + IS); 14 – Ti-6Al-4Mo; 15 – Ti-6Al-4Mo (HR)
G.V. Klevtsov, R.Z. Valiev, N.A. Klevtsova, I.P. Semenova, I.N. Pigaleva, M.L. Linderov
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Year: 2020 Volume: 10     Issue: 1 Pages: 16-21


The deformation structural transition is the transition of the material structure to the state of anomalous plasticity as a result of the combined action of thermal fluctuations, static displacements and dynamic oscillatory displacements of standing sound waves formed on natural resonators in the localization of the deformation of the sample

Accumulation of deformation and acoustic emission in aluminum-magnesium alloy AMg6 in the conditions of deformation of the structural transition

The deformation structural transition is the transition of the material structure to the state of anomalous plasticity as a result of the combined action of thermal fluctuations, static displacements and dynamic oscillatory displacements of standing sound waves formed on natural resonators in the localization of the deformation of the sample
S.V. Makarov, V.A. Plotnikov
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Year: 2020 Volume: 10     Issue: 1 Pages: 27-32

The paper presents the results of computer simulation using the molecular dynamics method of synthesizing binary Cu-Au nanoclusters by condensation from a gaseous phase. For the analysis, we selected the initial configurations of different chemical composition Cu3Au, Cu-Au, Cu90Au10, Cu60Au40 which were cooled with liquid nitrogen in the condensation process. Accord-ing to the simulation results, a relationship was found between the number of clusters formed at the first stage of synthesis and the percentage of gold atoms in the primary gaseous medium.

Analysis of the size distribution of binary Cu-Au nanoparticles during synthesis from a gaseous medium

The paper presents the results of computer simulation using the molecular dynamics method of synthesizing binary Cu-Au nanoclusters by condensation from a gaseous phase. For the analysis, we selected the initial configurations of different chemical composition Cu3Au, Cu-Au, Cu90Au10, Cu60Au40 which were cooled with liquid nitrogen in the condensation process. Accord-ing to the simulation results, a relationship was found between the number of clusters formed at the first stage of synthesis and the percentage of gold atoms in the primary gaseous medium.
Y.Y. Gafner, S.L. Gafner, Z.V. Golovenko
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Year: 2020 Volume: 10     Issue: 1 Pages: 33-37

The laws governing the development of localization of plastic deformation under the conditions of manifestation of the effect of space-time heterogeneity (Portevin-Le Chatelier effect) are investigated. The deformation diagram of an aluminum alloy, illustrates the multiple fluctuations of the flow stress, which detect qualitatively excellent dynamics in different parts of the deformation curve. Statistical distributions of the intervals between the plastic flow stress fluctuations were analyzed, and two critical points were found that indicate a change in the mechanisms of plastic deformation.

Statistical patterns of deformation localization during plastic flow in the AMg6 alloy

The laws governing the development of localization of plastic deformation under the conditions of manifestation of the effect of space-time heterogeneity (Portevin-Le Chatelier effect) are investigated. The deformation diagram of an aluminum alloy, illustrates the multiple fluctuations of the flow stress, which detect qualitatively excellent dynamics in different parts of the deformation curve. Statistical distributions of the intervals between the plastic flow stress fluctuations were analyzed, and two critical points were found that indicate a change in the mechanisms of plastic deformation.
D.V. Efremov, S.V. Uvarov, L.V. Spivak, O.B. Naimark
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Year: 2020 Volume: 10     Issue: 1 Pages: 38-42

It has been established that under shear deformation during SHS extrusion, the modification of Ti – B – Fe with small additions of nano-sized aluminum nitride powder leads to the refinement of the grain structure of the material. As a result of a decrease in the grain of the main phase, the microhardness of the material increases, on average, by 10%.

The effect of aluminum nitride nanoparticles on the structure, phase composition and properties of materials of the Ti-B-Fe system obtained by SHS-extrusion

It has been established that under shear deformation during SHS extrusion, the modification of Ti – B – Fe with small additions of nano-sized aluminum nitride powder leads to the refinement of the grain structure of the material. As a result of a decrease in the grain of the main phase, the microhardness of the material increases, on average, by 10%.
A.V. Bolotskaia, M.V. Mikheev, P.M. Bazhin, A.M. Stolin
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Year: 2020 Volume: 10     Issue: 1 Pages: 43-47
Journal section: Structure design and analysis


Ti-40wt.% Nb alloy in UFG state (structural elements’ average size is 0.28 μm) has multiphase structure, which is represented by β-subgrains, dispersive-strengthened with nanoparticles of nanosized ω-phase, and α-subgrains. Annealing temperature range of 773-973 K is characterized by transformation of alloy’s structure from ultrafingerained state into finegrained, active growth of dispersive-strengthened β-phase’s grains size and significant decrease of microhardness. Transformation occurs according to the α→β scheme.

Microstructure of ultrafine-grained Ti-40 wt.% Nb alloy after annealing

Ti-40wt.% Nb alloy in UFG state (structural elements’ average size is 0.28 μm) has multiphase structure, which is represented by β-subgrains, dispersive-strengthened with nanoparticles of nanosized ω-phase, and α-subgrains. Annealing temperature range of 773-973 K is characterized by transformation of alloy’s structure from ultrafingerained state into finegrained, active growth of dispersive-strengthened β-phase’s grains size and significant decrease of microhardness. Transformation occurs according to the α→β scheme.
A.Y. Eroshenko, Y.P. Sharkeev, M.A. Khimich, I.A. Glukhov, P.V. Uvarkin, A.I. Tolmachev, A.M. Mairambekova
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Year: 2020 Volume: 10     Issue: 1 Pages: 54-59
Journal section: Structure design and analysis


Spherical particles extracted from the brass cathode (a) and the distribution map of elements (iron - (b), copper - (c), zinc - (d)), showing the dominance of iron in the particles

Transmutation of a part of the extracted material of brass electrodes with pulses of electric current in an aqueous solution of NaCl

Spherical particles extracted from the brass cathode (a) and the distribution map of elements (iron - (b), copper - (c), zinc - (d)), showing the dominance of iron in the particles
M.P. Kashchenko, V.F. Balakirev, N.M. Kashchenko, M.B. Smirnov, Y.L. Chepelev, V.V. Ilyushin, N.V. Nikolaeva, V.G. Pushin
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Year: 2020 Volume: 10     Issue: 1 Pages: 66-71

The structure of CaCu3Ti4O12 equivalent circuit reveals three processes possible within the material – reach-through conductivity and two overlapping polarization processes – electronic and dipole relaxation ones. Temperature dependencies of specific conductivity in the Arrhenius scale for CaCu3Ti4O12 samples of different thicknesses are linear and characterized by activation energy of 1.05 eV. Temperature dependencies of electric parameters of samples are at their minimums at T = 350 C, which can be explained by the changed polarization mechanism.

Impedance spectroscopy of СaCu3Ti4O12

The structure of CaCu3Ti4O12 equivalent circuit reveals three processes possible within the material – reach-through conductivity and two overlapping polarization processes – electronic and dipole relaxation ones. Temperature dependencies of specific conductivity in the Arrhenius scale for CaCu3Ti4O12 samples of different thicknesses are linear and characterized by activation energy of 1.05 eV. Temperature dependencies of electric parameters of samples are at their minimums at T = 350 C, which can be explained by the changed polarization mechanism.
N.A. Sekushin, L.A. Koksharova, N.A. Zhuk
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Year: 2020 Volume: 10     Issue: 1 Pages: 72-77

The superelasticity at stress-induced α–γ'-martensitic transformation at room temperature in compression was 6.2 % and 5 % in [001]-oriented Fe43.5Mn34Al15Ni7.5 (at. %) single crystals and Fe42.5Mn34Al15Ni7.5Ti1 (at.%) oligocrystals, respectively. Single crystals exhibited good stability of superelasticity in isothermal loading/unloading cycles, in contrast to oligocrystals.

Superelasticity and its cyclic stability in [001]-oriented single crystals and oligocrystals of FeMnAlNi alloy in compression

The superelasticity at stress-induced α–γ'-martensitic transformation at room temperature in compression was 6.2 % and 5 % in [001]-oriented Fe43.5Mn34Al15Ni7.5 (at. %) single crystals and Fe42.5Mn34Al15Ni7.5Ti1 (at.%) oligocrystals, respectively. Single crystals exhibited good stability of superelasticity in isothermal loading/unloading cycles, in contrast to oligocrystals.
V.V. Poklonov, I.V. Kuksgauzen, Y.I. Chumlyakov, D.A. Kuksgauzen, V.A. Kirillov
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Year: 2020 Volume: 10     Issue: 1 Pages: 78-82

Solid solution «amorphisation» is observed at heating in the temperature range corresponding to α-γ transformation (920-960°C). Amorphous-like material state is retained both at subsequent heating (to 1060 °C) and cooling (to 20 °С), which is super-stable compared to the established metallic glasses.

Solid state amorphization in a thin Fe-Si-Mg-O surface film triggered by the reduction of elements from oxides in the temperature range of the α-γ transformation

Solid solution «amorphisation» is observed at heating in the temperature range corresponding to α-γ transformation (920-960°C). Amorphous-like material state is retained both at subsequent heating (to 1060 °C) and cooling (to 20 °С), which is super-stable compared to the established metallic glasses.
M.L. Lobanov, A.S. Yurovskikh, P.L. Reznik, N.N. Nikul’chenkov, G.M. Rusakov, A.A. Redikul’tsev
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Year: 2020 Volume: 10     Issue: 1 Pages: 83-88
Journal section: Structure design and analysis




The graphs of the dependences of heat resistance on the Larson-Miller parameter have the form characteristic of all the alloys studied, but for each melting composition there are individual characteristics. The calculated and experimental values of heat resistance have satisfactory convergence.

Modeling of changes in heat resistance of nickel-based alloys using Bayesian artificial neural networks

The graphs of the dependences of heat resistance on the Larson-Miller parameter have the form characteristic of all the alloys studied, but for each melting composition there are individual characteristics. The calculated and experimental values of heat resistance have satisfactory convergence.
O.V. Anoshina, A.S. Trubnikova, O.B. Milder, D.A. Tarasov, A.A. Ganeev, A.G. Tyagunov
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Year: 2020 Volume: 10     Issue: 1 Pages: 106-111

With a free upsetting of the Cu-0.6Cr alloy by ≈90% (е≈2.0), a decrease in the cooling rate of the material leads to an increase in the fraction of mid-angle boundaries and a decrease in the fraction of high-angle boundaries, primarily due to a decrease in the number of twin boundaries.

Structural changes of the Cu-0.6Cr alloy upon cooling at different rates after a large high-temperature deformation

With a free upsetting of the Cu-0.6Cr alloy by ≈90% (е≈2.0), a decrease in the cooling rate of the material leads to an increase in the fraction of mid-angle boundaries and a decrease in the fraction of high-angle boundaries, primarily due to a decrease in the number of twin boundaries.
D.A. Aksenov, G.I. Raab, R.N. Asfandiyarov
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Year: 2020 Volume: 10     Issue: 1 Pages: 112-117
Journal section: Structure design and analysis