Oxide surface layer and solid-phase weldability of titanium alloys

R.Y. Lutfullin, M.K. Mukhametrakhimov show affiliations and emails
Received 02 August 2021; Accepted 25 August 2021;
This paper is written in Russian
Citation: R.Y. Lutfullin, M.K. Mukhametrakhimov. Oxide surface layer and solid-phase weldability of titanium alloys. Lett. Mater., 2021, 11(3) 363-366
BibTex   https://doi.org/10.22226/2410-3535-2021-3-363-366

Abstract

The oxide layer in the zone of solid-phase joint (SPJ) of ultrafine-grained titanium alloy VT6. The observed oxide layer reduces the shear strength of the SPJ by more than 2 times.It is known that the ultrafine-grained (UFG) structure in alloys is thermally unstable. An important task for the modern aviation engineering is to preserve the UFG structure in parts for responsible purposes after their production in order to maintain the high level of their mechanical properties. In particular, the solution to this task necessitates the reduction of the temperature of solid-phase bonding while ensuring the necessary quality of the permanent joint. It is known that along with the average grain size, the oxide surface layer can also significantly affect the solid-phase weldability of titanium alloys at low temperatures, but the latter has been extremely poorly studied. In this regard, the influence of an oxide film is considered for domestic two-phase titanium alloys VT6 (Ti-Al-V system) and VT8 (Ti-Al-Mo system), which differ in the main alloying element for the stabilization of the β-phase. As a result of the experiments, the absence of an oxide layer in the zone of solid-phase connection of the ultrafine-grained (UFG) VT6 alloy after welding in vacuum at a reduced temperature of 600°C was metallographically revealed. This has a positive effect on the quality of welded samples according to the conducted mechanical tests. A continuous oxide layer was found in the solid-phase joint zone after welding at a temperature of 600°C for the UFG alloy VT8. The experimental results indicate that the UFG titanium alloy VT6, doped with relatively “mobile” vanadium, has the potential to reduce the lower temperature of solid-phase welding in vacuum by 50°C in comparison with the titanium alloy VT8.

References (21)

1. Z. A. Munir. Supplement to the Welding Journal. December. 333s (1983).
2. E. S. Karakozov. Pressure welding of metals. Moscow, Machine-Building (1986) 280 p. (in Russian) [Э. С. Каракозов. Сварка металлов давлением. Москва. Машиностроение (1986) 280 с.].
3. F. Pitt, M. Ramulu. JMEPEG. 13 (6), 727 (2004). Crossref
4. F. C. Campbell. Manufacturing technology for aerospace structural materials. Amsterdam. Boston. Heidelberg. London, New York, Oxford, Paris, San Diego, San Francisco, Singapore, Sydney, Tokyo, Elsevier Ltd. (2006).
5. R. Ya. Lutfullin, O. A. Kaibyshev, R. V. Safiullin, O. R. Valiakhmetov, M. Kh. Mukhametrakhimov. Acta Metallurgica Sinica (English Letters). 13 (2), 561 (2000).
6. R. Ya. Lutfullin. Letters on Materials. 1 (1), 59 (2011). (in Russian) [Р. Я. Лутфуллин. Письма о материалах. 1 (1), 59 (2011).]. Crossref
7. M. Kh. Mukhametrakhimov. Letters on Materials. 2 (4), 249 (2012). (in Russian) [М. Х. Мухаметрахимов. Письма о материалах. 2 (4), 249 (2012).]. Crossref
8. M. Kh. Mukhametrakhimov, R. Ya. Lutfullin. Proceedings of International Conference “Current status of Theory and Practice of Superplasticity in Materials”. Ufa. Gilem (2000) p. 118. (in Russian) [М. Х. Мухаметрахимов, Р. Я. Лутфуллин. Труды Международной научной конференции «Современное состояние теории и практики сверхпластичности материалов». Уфа, Гилем (2000) c. 118.].
9. R. Ya. Lutfullin, O. A. Kaibyshev, R. V. Safiullin, O. R. Valiakhmetov, M. Kh. Mukhametrahimov. Acta Metallurgica Sinica (English Letters). 13 (2), 561 (2000).
10. R. Ya. Lutfullin, O. A. Kaibyshev, O. R. Valiakhmetov, M. Kh. Mukhametrakhimov, R. V. Safiullin, R. R. Mulyukov. Advanced Materials. 4, 21 (2003). (in Russian) [Р. Я. Лутфуллин, О. А. Кайбышев, О. Р. Валиахметов, М. Х. Мухаметрахимов, Р. В. Сафиуллин, Р. Р. Мулюков. Перспективные материалы. 4, 21 (2003).].
11. R. Ya. Lutfullin, M. Kh. Mukhametrakhimov. Metal Science and Heat Treatment. 2, 11 (2006). (in Russian) [Р. Я. Лутфуллин, М. Х. Мухаметрахимов. Металловедение и термическая обработка материалов. 2, 11 (2006).].
12. O. A. Kaibyshev, R. V. Safiullin, R. Y. Lutfullin, V. V. Astanin. J. Mater. Eng. Perform. 8 (2), 205 (1999). Crossref
13. R. Ya. Lutfullin. Letters on Materials. 1 (2), 88 (2011). (in Russian) [Р. Я. Лутфуллин. Письма о материалах. 1 (2), 88 (2011).]. Crossref
14. U. Zwicker. Titan und Titanlegierungen. Moscow, Metallurgy (1979). (in Russian) [У. Цвиккер. Титан и его сплавы. Москва, Металлургия (1979) 512 с.].
15. G. Lütjering, J. C. Williams. Titanium, 2nd edition. Berlin, Heidelberg, New York, Springer (2007).
16. S. Z. Bokshtein, N. P. Zulina, O. V. Markovich. The Physics of Metals and Metallography. 4, 129 (1990). (in Russian) [С. З. Бокштейн, Н. П. Зюлина, О. В. Маркович. Физика металлов и металловедение. 4, 129 (1990).].
17. M. Kh. Mukhametrakhimov, R. Ya. Lutfullin. Fundamental’nye Problemy Sovremennogo Materialovedenia. 14 (4), 523 (2017). (in Russian) [М. Х. Мухаметрахимов, Р. Я. Лутфуллин. Фундаментальные проблемы современного материаловедения. 14 (4), 523 (2017).].
18. R. Ya. Lutfullin, O. A. Kaibyshev, R. V. Safiullin, O. R. Valiakhmetov, M. Kh. Mukhametrahimov, R. V. Safiullin, R. R. Mulyukov. Journal of Advanced Materials. 10 (4), 326 (2003).
19. G. A. Salishchev, O. R. Valiakhmetov, R. M. Galeyev, F. H. Froes. Materials Science Forum. 447 - 448, 441 (2004). Crossref
20. R. Ya. Lutfullin, M. Kh. Mukhametrakhimov. Metallovedenie I Termicheskaya Obrabotka Metallov. 2 (608), 11 (2006). (in Russian) [Р. Я. Лутфуллин, М. Х. Мухаметрахимов. Металловедение и термическая обработка металлов. 2 (608), 11 (2006).].
21. S. L. Semiatin, P. N. Fagin, J. F. Betten, A. P. Zane, A. K. Ghosh, G. A. Sargent. Metallurgical and Materials Transactions A. 41A, 499 (2010). Crossref

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Funding

1. The present work was accomplished according to the state assignment of IMSP RAS - № АААА-А17-117041310221-5.