Effect of the morphology of films of polyaniline derivatives poly-2-[(2E)-1‑methyl-2‑butene-1‑yl]aniline and poly-2-(cyclohex-2‑en-1‑yl)aniline on sensory sensitivity to humidity and ammonia vapors

R.B. Salikhov, I.N. Mullagaliev, B.R. Badretdinov, A.D. Ostaltsova, T.T. Sadykov, A.G. Mustafin show affiliations and emails
Received 10 June 2022; Accepted 12 September 2022;
Citation: R.B. Salikhov, I.N. Mullagaliev, B.R. Badretdinov, A.D. Ostaltsova, T.T. Sadykov, A.G. Mustafin. Effect of the morphology of films of polyaniline derivatives poly-2-[(2E)-1‑methyl-2‑butene-1‑yl]aniline and poly-2-(cyclohex-2‑en-1‑yl)aniline on sensory sensitivity to humidity and ammonia vapors. Lett. Mater., 2022, 12(4) 309-315
BibTex   https://doi.org/10.22226/2410-3535-2022-4-309-315

Abstract

Multilayer structures of resistive sensors  based on thin polymer films, SEM images of microstructures of film samples and calibration characteristicsThe influence of the morphology of polyaniline derivatives on the electrical conductivity, sensory sensitivity to air humidity of thin-film structures based on them, and the reaction to ammonia vapors has been investigated. Aniline derivatives, as well as polymers based on them, poly-2-[(2E)-1‑methyl-2‑butene-1‑yl]aniline and poly-2-(cyclohex-2‑en-1‑yl), were synthesized. Using a scanning electron microscope, the morphology of the surface of thin films obtained from a solution of synthesized polymers by centrifugation on sitall substrates was studied. Studying the nature of morphology is extremely important when creating sensory devices. On the basis of these polymers, samples of resistive thin-film structures were prepared, the dependence of their electrical conductivity on the relative humidity of the air and the dependence of the current passing through the sample with a change in the concentration of ammonia vapors were measured. The influence of the morphology of the surface of the films on the sensitivity of sensors to air humidity has been experimentally revealed and the prospects of using the studied films in humidity sensors have been shown. According to the experimental data, it can be seen that poly-2-[(2E)-1‑methyl-2‑butene-1‑yl] aniline film has the highest conductivity at the same values of relative humidity.

References (55)

1. B. Adhikari, S. Majumdar. Prog. Polym. Sci. 29, 699 (2004). Crossref
2. Q. Qi, T. Zhang, Q. J. Yu, R. Wang, Y. Zeng, L. Liu, H. B. Yang. Sens. Actuators B. 133, 638 (2008). Crossref
3. Q. Qi, T. Zhang, L. J. Wang. Appl. Phys. Lett. 93, 023105 (2008). Crossref
4. M. V. Arularasu, R. Sundaram, C. M. Magdalane, K. Kanimozhi, K. Kaviyarasu, F. T. Thema, D. Letsholathebe, G. T. Mola, M. Maaza. J Nanostruct. 7, 47 (2017). Crossref
5. W. Xuan, X. He, J. Chen, W. Wang, X. Wang, Y. Xu, Z. Xu, Y. Q. Fu, J. K. Luo. Nanoscale. 7 (16), 7430 (2015). Crossref
6. Y. Sakai, Y. Sadaoka, M. Matsuguchi. Sens. Actuators B. 35, 85 (1996). Crossref
7. Z. Chen, C. Lu. Sens. Lett. 3, 274 (2005). Crossref
8. Y. Sun, S. Seetharaman, Q. Liu, Z. Zhang, L. Liu, X. Wang. Energy. 114, 165 (2016). Crossref
9. D. Kassotis, R. Luke, M. Denise, M. Isabelle, C. Adam, H. William, C. Susan. Sci. Total Environ. 557, 901 (2016). Crossref
10. M. Kaur, B. K. Dadhich, R. Singh, K. Ganapathi, T. Bagwaiya, S. Bhattacharya, A. K. Debnath, K. P. Muthe, S. C. Gadkari. Sens. Actuators B. 242, 389 (2017). Crossref
11. D. Zhang, J. Wu, Y. Cao. Sens. Actuators B. 287, 346 (2019). Crossref
12. H. Yang, S. Ma, H. Jiao, Q. Chen, Y. Lu, W. Jin, W. Li, T. Wang, X. Jiang, Z. Qiang, H. Chen. Sens. Actuators B. 245, 493 (2017). Crossref
13. M. Diana, W. Roekmijati, W. Suyud. EDP Sci. 73, 06003 (2018). Crossref
14. S. Bardócz. Trends Food Sci. Technol. 6 (10), 341 (1995). Crossref
15. B. Timmer, W. Olthuis, A. Van Den Berg. Sens. Actuators B Chem. 107, 666 (2005). Crossref
16. H. Y. Li, C. S. Lee, D. H. Kim, J. H. Lee. ACS Appl. Mater. Interfaces. 10, 27858 (2018). Crossref
17. H. J. Sharma, D. V. Jamkar, S. B. Kondawar. Proc. Mater. Sci. 10, 186 (2015). Crossref
18. C. Steffens, M. L. Corazza, E. Franceschi, F. Castilhos, P. S. Herrmann, J. V. Oliveira. Sensors and Actuators B: Chemical. 171 - 172, 627 (2012). Crossref
19. H. Xu, D. Ju, W. Li, H. Gong, J. Zhang, J. Wang, B. Cao. Sens. Actuators B. 224, 654 (2016). Crossref
20. M. T. S. Chani, K. S. Karimov, F. A. Khalid, S. A. Moiz. Solid State Sci. 18, 78 (2013). Crossref
21. M. Trchová, D. Jasenská, M. Bláha, J. Prokeš, J. Stejskal. Spectrochim Acta A Mol Biomol Spectrosc. 235, 118300 (2020). Crossref
22. M. V. Kulkarni, A. K. Viswanath. Polym. Eng. Sci. 47, 1621 (2007). Crossref
23. M. V. Kulkarni, A. K. Viswanath, R. C. Aiyer, P. K. Khanna, J. Polym. Sci. B: Polym. Phys. 43, 2161 (2005). Crossref
24. M. V. Kulkarni, A. K. Viswanath, P. K. Khanna. Sens. Actuators B Chem. 115, 140 (2006). Crossref
25. P. Zarrintaj, H. Vahabi, M. R. Saeb, M. Mozafari. In: Fundamentals and Emerging Applications of Polyaniline. Elsevier (2019) p. 259. Crossref
26. A. N. Andriianova, Yu. N. Biglova, A. G. Mustafin. RSC Adv. 10, 7468 (2020). Crossref
27. K. Amer, A. M. Elshaer, M. A. S. Ebrahim. J. Mater. Sci. Mater. Electron. 30 (1), 391 (2019). Crossref
28. G. Liao, Q. Li, Z. Xu. Prog. Org. Coat. 126, 35 (2019). Crossref
29. G. Ćirić-Marjanović. Synth. Met. 177, 1 (2013). Crossref
30. J. Vivekanandan, V. Ponnusamy, A. Mahudeswaran, P. Vijayanand. Arch. Appl. Sci. Res. 3, 147 (2011).
31. J. Liu, X. Hu. X. Wang, J. Yao, D. Sun, Z. Fan, M. Guo. Polym. Int. 63, 722 (2014). Crossref
32. J. Summers, S. Waware, M. Maduwa, A. Summers. Synth. Met. 209, 251 (2015). Crossref
33. T. Kabomo, M. Scurrell. Polym. Adv. Technol. 27, 759 (2016). Crossref
34. K. Khamngoen, N. Paradee, A. Sirivat. J. Polym. Res. 23, 172 (2016). Crossref
35. Y. Liu, S. Li, P. Yao, Q. Zhang. Int. J. Mod. Phys. B. 31, 1744091 (2017). Crossref
36. C. Barbero, H. Salavagione, D. Acevedo, D. Grumelli, F. Garay, G. Planes, M. Miras. Electrochim. Acta. 49, 3671 (2004). Crossref
37. U. S. Waware. J. Mater. Sci-Mater. El. 28 (20), 15178 (2017). Crossref
38. U. S. Waware, G. J. Summers, A. M. S. Hamouda, M. Rashid. Polym. Plast. Technol. Eng. 57, 1015 (2018). Crossref
39. F. Movahedifar, A. Modarresi-Alam. Polym. Adv. Technol. 27 (1), 131 (2016). Crossref
40. N. R. Tanguy, M. Thompson, N. Yan. Sens. Actuators B Chem. 257, 1044 (2018). Crossref
41. T. Zhang, H. Qi, Z. Liao, Y. D. Horev, L. A. Panes-Ruiz, P. S. Petkov, Z. Zhang, R. Shivhare, P. Zhang, K. Liu, V. Bezugly, S. Liu, Z. Zheng, S. Mannsfeld, T. Heine, G. Cuniberti, H. Haick, E. Zschech, U. Kaiser, R. Dong, X. Feng. Nat. Commun. 10, 1 (2019). Crossref
42. J. Zhao, X. Liu, Y. Wu, D. S. Li, Q. Zhang. Chem. Rev. 391, 30 (2019). Crossref
43. L. R. Latypova, A. N. Andriianova, S. M. Salikhov, I. B. Abdrakhmanov, A. G. Mustafin. Polymer International. 69 (9), 804 (2020). Crossref
44. R. B. Salikhov, Y. N. Biglova, Y. M. Yumaguzin, M. S. Miftakhov, A. G. Mustafin. Technical Physics Letters. 39 (10), 854 (2013). Crossref
45. Z. Du, C. Li, L. Li, H. Yu, Y. Wang, T. Wang. J. Mater. Sci. Mater. Electron. 22, 418 (2011). Crossref
46. A. N. Andrianova. New polyaniline derivatives: Physico-chemical properties, kinetics and mechanism of formation: PhD thesis. Bashkir State University, Ufa (2020) 185 p.
47. R. R. Gataullin. Directed intramolecular cyclization of ORTHO-alkenylanilines: PhD thesis. UNC RAS, Ufa (2004) 263 p.
48. A. Andriianova, A. Shigapova, Y. Biglova, R. Salikhov, I. Abdrakhmanov, A. Mustafin. Chinese Journal of Polymer Science. 37 (8), 774 (2019). Crossref
49. J. Stejskal, I. Sapurina, M. Trchova, J. Prokes, I. Krivika, E. Tobolkova. Macromolecules. 31 (7), 2218 (1998). Crossref
50. S. Quillard, G. Louarn, J. P. Buisson, M. Boyer, M. Lapkowski, A. Pron. Synth. Met. 84, 805 (1997). Crossref
51. J. G. Masters, Y. Sun, A. G. Macdiarmid, A. J. Epstein. Synthetic Metals. 41 (1-2), 715 (1991). Crossref
52. A. N. Andriianova, T. T. Sadykov, A. Mustafin. Chemistry Select. 6 (34), 8942 (2021). Crossref
53. D. Zhang, D. Wang, P. Li, X. Zhou, X. Zong, G. Dong. Sens. Actuators, B. 255 (2), 1869 (2018). Crossref
54. R. B. Salikhov, A. N. Lachinov, R. G. Rakhmeev, R. M. Gadiev, A. R. Yusupov, S. N. Salazkin. Measurement Techniques. 52 (4), 427 (2009). Crossref
55. A. N. Andriianova, R. B. Salikhov, L. R. Latypova, I. N. Mullagaliev, T. R. Salikhov, A. Mustafin. Sustainable Energy & Fuels. 6, 3435 (2022). Crossref

Funding

1. Ministry of Education and Science of the Russian Federation - This work was supported by the State assignment for the implementation of scientific research by laboratories (order MN-8/1356 of 09/20/2021).